Yes, it works, and very well. The flashes come with little stands so they can be set up in an instant. And they don't even need line of sight to your pop-up camera flash. They can be triggered by strong secondary reflections from the camera's flash. I have the Yongnuo radio controller but I much prefer the optical slave.Are you serious? Currently all it takes to use the flash on my a6000 is to pop the flash out. Would that really work?!
One thing to be careful of is to make sure your camera flash does not strongly illuminate the subject. There is a very slight delay between master and slave flash, and if both master and slave are strongly illuminating a vibrating subject, you can get ghosting.
The triggering time for the optical slave is faster than that for the radio slave. That means if you are using multiple Yongnuos, with one of them being used to control the others, they will not all fire together. The master will fire first and then the slaves. Again, this can cause ghosting if the subject is not absolutely still, at least if magnification is 10x or more.